Early solar system aqueous activity: K isotope evidence from Allende

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.     

Investigation of the elevation of saltwater wedge due to subsurface dams

Subsurface dams are rather effective and used for the prevention of saltwater intrusion in coastal regions around the world. We carried out the laboratory experiments to investigate the elevation of saltwater wedge after the construction of subsurface dams. The elevation of saltwater wedge refers to the upward movement of the downstream saltwater wedge because the subsurface dams obstruct the regional groundwater flow and reduce the freshwater discharge. Consequently, the saltwater wedge cannot further extend in the longitudinal direction but rises in the vertical profile resulting in significant downstream aquifer salinization. In order to quantitatively address this issue, field-scale numerical simulations were conducted to explore the influence of various dam heights, distances, and hydraulic gradients on the elevation of saltwater wedge. Our investigation shows that the upward movement of the saltwater wedge and its areal extension in the vertical domain of the downstream aquifer become more severe with a higher dam and performed a great dependence on the freshwater discharge. Furthermore, the increase of the hydraulic gradient and the dam distance from the sea boundary leads to a more pronounced wedge elevation. This phenomenon comes from the variation of the freshwater discharge due to the modification of dam height, location, and hydraulic gradient. Large freshwater discharge can generate greater repulsive force to restrain the elevation of saltwater wedge. These conclusions provide theoretical references for the behaviour of the freshwater–seawater interface after the construction of subsurface dams and help optimize the design strategy to better utilize the coastal groundwater resources.     

无人机技术在海岛测绘中的应用

为提高海岛测绘的技术手段，将无人机引入海岛地形调查中，以Swallow-P小型固定翼无人机开展惠州市大亚湾虎洲海岛大比例尺测图为例，系统归纳了无人机外业数据采集与内业数据处理的具体流程，并制作了DEM和DOM成果；经过实测地面点精度分析得出虎洲无人机大比例尺测图成果平面位置中误差和高程中误差符合1∶1000测图精度要求。     

中国工业烟粉尘排放时空演化及其影响因素

采用空间分析和空间杜宾模型等方法，研究1999—2017年中国工业烟粉尘排放时空演化特征及其影响因素。结果表明：① 中国工业烟粉尘排放空间分布差异明显，其排放的基尼系数和污染物分布指数均呈现下降态势，空间集中程度有所缓和。② 中国工业烟粉尘排放空间分布呈东北?西南走向，其排放中心不断由东南向西北方向迁移。③ 中国工业烟粉尘排放存在空间相关性和空间溢出效应，其冷热点区空间分布发生显著变化。④ 能源消耗、第二产业比重、人口密度和经济发展水平的提升将会增加工业烟粉尘排放，而外资水平、治理技术水平和环境规制力度的提升则有利于减少工业烟粉尘排放。     

基于LocaSpaceViewer的地理信息技术应用教学设计与反思

本文基于笔者运用LocaSpaceViewer软件完成人教版地理必修3“地理信息技术在区域地理环境研究中的应用”的教学内容,总结反思教学过程中出现的问题,并提出改进的建议和措施。     

贵州夜郎湖表层水体地球化学昼夜变化及其影响因素

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。     

Correspondence between the large volcanic eruptions and ENSO events over AD 1525–2000

ENSO is an interannual mode which may be affected by external forcing, such as volcanic eruptions. Based on the reconstructed volcanic eruptions chronology and ENSO sequences, both 195 large volcanic eruptions(VEI≥4) and 398 ENSO(El Ni?o and La Ni?a) events were extracted from 1525 to 2000. An analysis of the correspondence between the large volcanic eruptions and ENSO events was performed by matching the large volcanic eruptions with the types and magnitudes of ENSO events present in the 0–2 years after the eruptions. The results show the following:(1) The percentages of ENSO events within the 3 years after the large eruptions had increased to 68.3% from 31.7% compared with those with no-eruptions in the previous 0–2 years. In addition, the ratio of El Ni?o to La Ni?a events turned from 2:3 to 1:1, and more El Ni?o events occurred in the 0 year after eruptions in the low-latitudes of the Northern Hemisphere and in the tropics but more La Ni?a events occurred in the 0 year after in the high-latitudes of the Northern Hemisphere and the Southern Hemisphere.(2) After the eruptions, the weak(W) El Ni?o events had increased by 8 percentage points and the very strong(VS) El Ni?o events had decreased by 10 percentage points; conversely, there was a decrease by 15 percentage points of the weak La Ni?a events and an increase by 11.4 percentage points of the very strong La Ni?a events. Specifically, the percentages of strong La Ni?a events increased to a peak at 1(+1) year after the eruptions.(3) The percentage of eruptions followed by single-year ENSO was the greatest. The percentage of ENSO events that occurred in the consecutive 2 years following an eruption was approximately equal to the percentage of events that occurred consecutively 3 years following an eruption, and both sets of ENSO magnitudes showed a decreasing trend.     

Model tests on XCC-piled embankment under dynamic train load of high-speed railways

Piled embankments, which offer many advantages, are increasingly popular in construction of high-speed railways in China. Although the performance of piled embankment under static loading is well-known, the behavior under the dynamic train load of a high-speed railway is not yet understood. In light of this, a heavily instrumented piled embankment model was set up, and a model test was carried out, in which a servo-hydraulic actuator outputting M-shaped waves was adopted to simulate the process of a running train. Earth pressure, settlement, strain in the geogrid and pile and excess pore water pressure were measured. The results show that the soil arching height under the dynamic train load of a high-speed railway is shorter than under static loading. The growth trend for accumulated settlement slowed down after long-term vibration although there was still a tendency for it to increase. Accumulated geogrid strain has an increasing tendency after long-term vibration. The closer the embankment edge, the greater the geogrid strain over the subsoil. Strains in the pile were smaller under dynamic train loads, and their distribution was different from that under static loading. At the same elevation, excess pore water pressure under the track slab was greater than that under the embankment shoulder.     

Seismic imaging of the middle and upper crust by double-difference tomography: the Haicheng earthquake (Ms 7.3) in Liaoning Province

The Haicheng earthquake (Ms 7.3) occurred in Liaoning Province (39°N–43°N, 120°E–126°E ), China on February 4, 1975. The mortality rate was only 0.02% owing to the first timely and accurate prediction, although the area affected by the earthquake was 9200 km² and covered cities with a population density of 1000 p/km². In this study, the doubledifference (DD) tomography method was used to obtain high-resolution three-dimensional (3D) P- and S-wave velocity (Vp and Vs) structures and Vp/Vs as well as the earthquake locations. Tomography results suggest that velocity structure at shallow depth coincides well with topography and sediment thickness. The earthquake locations form a northwest-striking zone associated with the Jinzhou(JZ) Fault and a northeast-striking zone associated with the Haichenghe-Dayanghe (HD) Fault, and suggest that the JZ Fault consists of three faults and the Ms 7.3 Haicheng earthquake originated at the intersection of the JZ and the Faults. Lowvelocity zones (LVZs) with low Vp/Vs are observed at 15–20 km depth beneath the Haicheng (HC) region. We interpret the LVZs in the middle crust as regions of fluids, suggesting rock dehydration at high temperatures. The LVZs and low Vp/Vs in the upper crust are attributed to groundwater-filled cracks and pores. We believe that large crustal earthquakes in this area are caused by the combination of faulting and fluid movement in the middle crust.